Quantum kisses change the colour of nothing
New insights from research suggest ways to measure the world
at the scale of single atoms and molecules.
Nano-sized balls of gold
Image credit: M Hawkeye, NanoPhotonics, Cambridge
November 7, 2012
Even empty gaps have a colour. Now scientists have shown that quantum jumps of electrons can change the colour
of gaps between nano-sized balls of gold. The new results, published today in the journal Nature, set a fundamental
quantum limit on how tightly light can be trapped.
The team from the Universities of Cambridge, the Basque Country and Paris have combined tour de force experiments with
advanced theories to show how light interacts with matter at nanometre sizes. The work shows how they can literally see
quantum mechanics in action in air at room temperature.
Because electrons in a metal move easily, shining light onto a tiny crack pushes electric charges onto and off each crack face
in turn, at optical frequencies. The oscillating charge across the gap produces a ‘plasmonic’ colour for the ghostly region
in-between, but only when the gap is small enough.
Team leader Professor Jeremy Baumberg from the University of Cambridge Cavendish Laboratory suggests we think of this like
the tension building between a flirtatious couple staring into each other’s eyes. As their faces get closer the tension mounts,
and only a kiss discharges this energy.
In the new experiments, the gap is shrunk below 1nm (1 billionth of a metre) which strongly reddens the gap colour as the
charge builds up. However because electrons can jump across the gap by quantum tunnelling, the charge can drain away when
the gap is below 0.35nm, seen as a blue-shifting of the colour. As Baumberg says, “It is as if you can kiss without quite
Matt Hawkeye, from the experimental team at Cambridge, said: “Lining up the two nano-balls of gold is like closing your eyes
and touching together two needles strapped to the end of your fingers. It has taken years of practise to get good at it.”
Prof Javier Aizpurua, leader of the theoretical team from San Sebastian complains: “Trying to model so many electrons oscillating
inside the gold just cannot be done with existing theories.” He has had to fuse classical and quantum views of the world to even
predict the colour shifts seen in experiment.
The new insights from this work suggest ways to measure the world down to the scale of single atoms and molecules,
and strategies to make useful tiny devices.
The research is funded as part of a UK Engineering and Physical Sciences Research Council (EPSRC) investment in the
Cambridge NanoPhotonics Centre, as well as EU and Ikerbasque funding that joins the teams together.
This work is licensed under an attribution, noncommercial, share-alike Creative Commons Licence.
The original article can be read at
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